4.6 Article

Role of Sintering Temperature in Production of Nepheline Ceramics-Based Geopolymer with Addition of Ultra-High Molecular Weight Polyethylene

Journal

MATERIALS
Volume 14, Issue 5, Pages -

Publisher

MDPI
DOI: 10.3390/ma14051077

Keywords

geopolymer; ceramics; nepheline; lightweight; sintering

Funding

  1. Centre of Excellent Geopolymer and Green Technology (CeGeoGTech), UniMAP

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The main goal of developing ceramic materials using the geopolymer method is to reduce reliance on high sintering temperatures. By incorporating ultra-high molecular weight polyethylene (UHMWPE) as a binder, the physical and microstructural properties of nepheline ceramics based on geopolymers were enhanced. The study demonstrates that sintering temperatures significantly impact the properties of the materials, with the highest flexural strength achieved at 1200 degrees Celsius.
The primary motivation of developing ceramic materials using geopolymer method is to minimize the reliance on high sintering temperatures. The ultra-high molecular weight polyethylene (UHMWPE) was added as binder and reinforces the nepheline ceramics based geopolymer. The samples were sintered at 900 degrees C, 1000 degrees C, 1100 degrees C, and 1200 degrees C to elucidate the influence of sintering on the physical and microstructural properties. The results indicated that a maximum flexural strength of 92 MPa is attainable once the samples are used to be sintered at 1200 degrees C. It was also determined that the density, porosity, volumetric shrinkage, and water absorption of the samples also affected by the sintering due to the change of microstructure and crystallinity. The IR spectra reveal that the band at around 1400 cm(-1) becomes weak, indicating that sodium carbonate decomposed and began to react with the silica and alumina released from gels to form nepheline phases. The sintering process influence in the development of the final microstructure thus improving the properties of the ceramic materials.

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