Measurements of Density of Liquid Oxides with an Aero-Acoustic Levitator

Densities of liquid oxide melts with melting temperatures above 2000 degrees C are required to establish mixing models in the liquid state for thermodynamic modeling and advanced additive manufacturing and laser welding of ceramics. Accurate measurements of molten rare earth oxide density were recently reported from experiments with an electrostatic levitator on board the International Space Station. In this work, we present an approach to terrestrial measurements of density and thermal expansion of liquid oxides from high-speed videography using an aero-acoustic levitator with laser heating and machine vision algorithms. The following density values for liquid oxides at melting temperature were obtained: Y2O3 4.6 +/- 0.15; Yb2O3 8.4 +/- 0.2; Zr0.9Y0.1O1.95 4.7 +/- 0.2; Zr0.95Y0.05O1.975 4.9 +/- 0.2; HfO2 8.2 +/- 0.3 g/cm(3). The accuracy of density and thermal expansion measurements can be improved by employing backlight illumination, spectropyrometry and a multi-emitter acoustic levitator.

Automated summary

This study presents a method for measuring the density and thermal expansion of liquid oxides at their melting points using an aero-acoustic levitator with laser heating and machine vision algorithms. Accurate density values for several liquid oxides were obtained, providing essential data for thermodynamic modeling and material manufacturing. Further improvement in accuracy can be achieved through the use of backlight illumination, spectropyrometry, and a multi-emitter acoustic levitator.