Journal
ARABIAN JOURNAL OF CHEMISTRY
Volume 14, Issue 4, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.arabjc.2021.103103
Keywords
Thermoelectric; Thermal conductivity; Power factor; Power generation; Seebeck coefficient; Renewable energy
Categories
Funding
- King Fahd University of Petroleum and Minerals [DF191032]
- King Abdullah City for Atomic and Renewable Energy (K.A.CARE)
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This review discusses recent progress and challenges in achieving high thermoelectric figure of merit with inorganic materials, emphasizing methods to reduce thermal conductivity and maximize power factor to enhance thermoelectric performance. Specific advancements in materials like chalcogenides, Heusler compounds, clathrates, and skutterudites are highlighted, along with different fabrication techniques to tune thermoelectric performance. Future perspectives on utilizing a multi-scale approach to significantly tune both power factor and thermal conductivity for high-performance industrial applications are also discussed.
This review discusses the recent progress and persistent challenges toward achieving high thermoelectric (TE) figure of merit with inorganic TE materials. For decades, the interdependence between the relevant thermoelectric parameters has been the main impediment halting the large-scale usage of these materials for clean energy production. The thermoelectric performance can be improved by reducing the thermal conductivity or maximizing the power factor. We summarized the state-of-the-art methodologies adopted to reduce the lattice thermal conductivity to its amorphous limit, thus enhancing the figure of merit. The synergistic approach of utilizing valence band convergence, carrier filtering together with resonant levels formation has also been found to improve the power factor and the figure of merit of some TE materials. The work gives particular emphasis to systems in which spectacular advances have been demonstrated, such as chalcogenides, Heusler compounds, clathrates, and skutterudites. We further summarized different materials fabrication techniques with their success in tuning the TE performance. A discussion on future perspective where both the power factor and the thermal conductivity can be significantly tuned via a multi-scale approach to yield high-performance TE materials for industrial applications has been presented. (C) 2021 The Authors. Published by Elsevier B.V. on behalf of King Saud University.
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