Journal
TETRAHEDRON LETTERS
Volume 68, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2021.152897
Keywords
Copper-catalysed; Aryl boronic acid; Se-(difluoromethyl) 4-methylbenzenesulfonoselenoate
Categories
Funding
- Natural Science Foundation of Tianjin City [18JCQNJC76600]
- National Natural Science Foundation of China [21572158]
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In this study, a novel method for the synthesis of aryl difluoromethylselenylether was developed by copper-catalysed direct difluoromethylselenolation of aryl boronic acids. This method offers a broad substrate scope, utilizes cheap and readily accessible reagents, and operates under mild reaction conditions.
In this study, we developed the first copper-catalysed direct difluoromethylselenolation of aryl boronic acids using Se-(difluoromethyl) 4-methylbenzenesulfonoselenoate as a difluoromethylselenolation reagent. Owing to the cheap and readily accessible reagents, broad substrate scope, and mild reaction conditions, this is an alternative and practical strategy for the synthesis of aryl difluoromethylselenylether. (C) 2021 Published by Elsevier Ltd.
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