4.7 Article

Silane-based coating charged with TiO2 NPs for dental implant applications

Journal

SURFACE & COATINGS TECHNOLOGY
Volume 413, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.surfcoat.2021.127066

Keywords

Dental implants; Locking agent; Anti-wear coating; Sol-gel coating; Dental abutments; Screw loosening

Funding

  1. Portugal 2020 [POCI-01-0247-FEDER-017982]

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To enhance the long-term stability of a dental implant, a protective coating containing TiO2 nanoparticles is proposed for selected parts using GPTMS/TEOS sol-gel coating. This coating effectively improves the anti-loosening properties of the abutment screw and achieves high locking efficacy and anti-wear performance due to its advantageous mechanical properties. The incorporation of TiO2 NPs in the polymeric backbone of the coating improves resistance to hydrolytic degradation and reduces hardness and Young modulus.
In modern dentistry, various techniques are being used to enhance longevity of a tooth implant. Among the most attractive solutions to promote the long-term stability of a dental implant, is the application of a protective coating on selected parts of the assembly. In this paper, the use of 3-(glycidyloxypropyl)trimethoxysilane and tetraethyl orthosilicate (GPTMS/TEOS) sol-gel coating containing TiO2 nanoparticles is proposed as a locking agent to improve long-term stability of a dental implant. The concept is based on an approach used in machine industry, i.e. enhancing the frictional engagement between the mating parts and therefore preventing their unintentional loosening. Compared with samples not subjected to surface modification, the proposed coating is effective in terms of improving the anti-loosening properties of the abutment screw. High locking efficacy of the sol-gel film, as well as its anti-wear performance, is achieved by the advantageous mechanical properties of the coating. Compared with a pure GPTMS/TEOS matrix, the incorporation of TiO2 NPs in the polymeric backbone results in an improvement of the resistance to hydrolytic degradation, as well as reduction of hardness and Young modulus of the coating.

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