3D Thioether-Based Covalent Organic Frameworks for Selective and Efficient Mercury Removal

Developing functionalized 3D covalent organic frameworks (3D COFs) is critical to broaden their potential applications. However, the introduction of specific functionality in 3D COFs remains a great challenge because most of the functional groups are not compatible with the synthesis conditions. Herein, for the first time 3D thioether-based COFs (JUC-570 and JUC-571) for mercury (Hg2+) removal from aqueous solution is reported. These 3D thioether-based COFs prepared by the bottom-up approach display high Hg2+ uptakes (972 mg g(-1) for JUC-570 and 970 mg g(-1) for JUC-571 at pH = 5), fast adsorption kinetics (distribution coefficient K-d value of 2.29 x 10(7) mL g(-1) for JUC-570 and 2.07 x 10(7) mL g(-1) for JUC-571), and favorable selectivity. In particular, JUC-570 is periodically decorated with isopropyl groups around imine bonds that markedly improve its chemical stability and effectively prevent the pore collapse, and thus endows high Hg2+ adsorption capacity (619 mg g(-1)) and excellent cycle performance even at pH = 1. This study not only puts forward a new route to construct stable functionalized 3D COFs, but also promotes their potential applications in areas related to the environment.

Automated summary

The study reports the use of thioether-based 3D COFs for mercury removal, demonstrating high adsorption capacity, speed, and selectivity. Particularly, JUC-570 shows exceptional chemical stability and cycling performance, offering a new method for constructing stable functionalized 3D COFs.