Interfacing Carbon Dots for Charge-Transfer Processes

Carbon dots (CDs) are a booming material and the most recent incomer in the big family of carbon nanostructures. Specifically, CDs are nanosized fluorescent core-shell nanoparticles with tunable absorption and emission spectra, with high solubility in aqueous media and common organic solvents. Herein, the origins and the development of these unique nanoscale structures are discussed, key synthetic routes are briefly described, and the utilization of CDs in light-induced charge-transfer schemes is mainly focused upon. Beyond the impact of the CD's surface on the photoluminescence properties, functionalization, by covalent or supramolecular means, permits controllable incorporation of new functionalities with novel photophysical properties. Furthermore, the dual nature of CDs as electron donating or electron accepting species, unveiled upon interfacing them with organic chromophores, highlights their potentiality in managing diverse charge-transfer processes. Novel mechanisms, such as symmetry-breaking photoinduced charge-transfer can be activated upon covalent functionalization of CDs with organic dyes. Without a doubt, participation of CDs in energy conversion schemes opens up a wide avenue that may lead to the development of novel prototype devices suitable for technological applications and related to photonics and optoelectronics.

Automated summary

Carbon dots (CDs) are nanosized fluorescent core-shell nanoparticles with tunable absorption and emission spectra, widely used in light-induced charge-transfer schemes and capable of incorporating new functionalities through functionalization.