4.6 Article

Synthesis of Cu2O-Modified Reduced Graphene Oxide for NO2 Sensors

Journal

SENSORS
Volume 21, Issue 6, Pages -

Publisher

MDPI
DOI: 10.3390/s21061958

Keywords

reduced graphene oxide (rGO); cuprous oxide nanowires; polypyrrole; gas sensors; NO2 sensing; p-type semiconductor

Funding

  1. National Natural Science Foundation of China [61871281, 51,302,179, 61574086]
  2. MOST of China [SQ2018YFE010343]
  3. Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions

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A novel composite material composed of two p-type semiconductors, cuprous oxide and graphene oxide, was synthesized and used to assemble a p-p-type gas sensor for NO2 detection. The resulting nanocomposite demonstrated excellent sensitivity, reversibility, repeatability, and selectivity in detecting NO2 gas at low concentrations.
Nowadays, metal oxide semiconductors (MOS)-reduced graphene oxide (rGO) nanocomposites have attracted significant research attention for gas sensing applications. Herein, a novel composite material is synthesized by combining two p-type semiconductors, i.e., Cu2O and rGO, and a p-p-type gas sensor is assembled for NO2 detection. Briefly, polypyrrole-coated cuprous oxide nanowires (PPy/Cu2O) are prepared via hydrothermal method and combined with graphene oxide (GO). Then, the nanocomposite (rGO/PPy/Cu2O) is obtained by using high-temperature thermal reduction under Ar atmosphere. The results reveal that the as-prepared rGO/PPy/Cu2O nanocomposite exhibits a maximum NO2 response of 42.5% and is capable of detecting NO2 at a low concentration of 200 ppb. Overall, the as-prepared rGO/PPy/Cu2O nanocomposite demonstrates excellent sensitivity, reversibility, repeatability, and selectivity for NO2 sensing applications.

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