4.7 Article

A novel thermoanalytical method for quantifying microplastics in marine sediments

Journal

SCIENCE OF THE TOTAL ENVIRONMENT
Volume 760, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.scitotenv.2020.144316

Keywords

Microplastic; Quantification method; Microplastic-derived carbon (MPC); Marine sediment core; The Yellow Sea

Funding

  1. National Natural Science Foundation of China [41703043, 41673066]
  2. Funds of Guangdong Research and Construction of Public Service Abilities [2017B020218004]
  3. Natural Science Foundation of Guangdong Province [18zxxt31]
  4. National Basic Research Program of China (973 Program) [2012CB956004]
  5. National Oil and Gas Major Project [2017ZX05008-002-050]

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A novel thermoanalytical method for quantifying microplastics by measuring the contents of microplastic-derived carbon has been proposed in this study, which effectively eliminates the limitation of particle appearances. Case study demonstrates the high reliability and practicability of this method in quantifying microplastics.
Microplastic pollution in marine environments is of particular concern on its risk to the ecosystem. To assess and manage microplastic contaminants, their quantitative detection in environmental samples is a high priority. However, uncertainties of current methods still exist when estimating their abundances, particularly with fine-grained (<1mm) microplastics. This work reports a novel thermoanalytical method for quantifying microplastics by measuring the contents of microplastic-derived carbon (MPC) in samples under the premise of nearly eliminating the limit of their particle appearances. After validating the method via samples with the spiked microplastics, we have conducted a case study on sediment core H43 that spanned 1925-2009 CE from the Yellow Sea for further illustrating the high reliability and practicability of this method for quantifying microplastics in natural samples. Our results have demonstrated that the proposed method may be a promising technique to determine the mass-related concentrations of the total microplastics in marine sediments for evaluating their pollution status and quantitative contribution to marine carbon storage. (C) 2020 Elsevier B.V. All rights reserved.

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