Journal
PROGRESS IN ORGANIC COATINGS
Volume 151, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.porgcoat.2020.106099
Keywords
Hydrogen bond complex; Visible light photoinitiating system; Photobleaching; Water solubility
Funding
- National Key Research and Development Program of China [2017YFB0307800]
- Beijing Laboratory of Biomedical Materials
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The newly synthesized photoinitiator and hydrogen bond complex demonstrate high photoreactivity and dispersibility in visible light polymerization, making them potentially useful for photo-induced organic coatings.
A type II photoinitiator (2E,6E)-2,6-bis((1H-pyrrol-2-yl)methylene)cyclohexan-1-one(BPC) was conveniently synthesized through Claisen-Schmidt reaction. Hydrogen bond complex BFC/TEOA not only exhibits high photoreactivity on the visible light polymerization, but also shows rapid bleach, excellent dispersibility in water which could be potential for photo-induced organic coating.
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