4.7 Article

Analysis of hematite attrition in a grid jet apparatus

Journal

POWDER TECHNOLOGY
Volume 380, Issue -, Pages 377-384

Publisher

ELSEVIER
DOI: 10.1016/j.powtec.2020.11.002

Keywords

Attrition; Fragmentation; Abrasion; Powder; Chemical looping; Hematite; Population balance

Funding

  1. Department of Energy through the office of Fossil Energy's Advanced Combustion funding program
  2. U.S. Department of Energy

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This study investigates the attrition of hematite particles using a modified ASTM apparatus, revealing a severe variation in particle size distributions that decreases over time. By fitting weight fractions of the sieves over time to a linear, time-variant population balance model, insights into particle attrition were gained. The first-order rate constant was modified as a decaying exponential to better understand particle attrition behavior.
Particulate attrition is of interest for novel carbon-capture processes such as chemical looping combustion because the makeup cost of oxygen carrier is a significant portion of operating cost. Thus, models to study and predict attrition of various oxygen carriers in fluidized bed systems are being developed. One of the regions of concern in fluidized bed systems is the high-velocity jet region near gas distributors in a fluid bed. This work studies the attrition of hematite particles using a modified ASTM apparatus to measure the particle size distribution throughout the experiment. Bed weight and gas velocity were varied. Hematite particles above the corresponding threshold value had a severe variation of particle size distributions which decreased with time. Weight fractions of the sieves over time were fit to a linear, time-variant population balance model to offer insight into particle attrition. The first-order rate constant was modified as a decaying exponential. Published by Elsevier B.V.

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