4.5 Article

Development of a highly efficient selective flocculant based on functionalized β-cyclodextrin toward beneficiation of low-quality iron ore

Journal

POLYMERS FOR ADVANCED TECHNOLOGIES
Volume 32, Issue 5, Pages 2169-2175

Publisher

WILEY
DOI: 10.1002/pat.5247

Keywords

flocculation; β ‐ cyclodextrin; copolymer

Funding

  1. Tata Steel Ltd., Jamshedpur [RD/PROP/COL/506/2020]

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The study focused on the development of a novel flocculant utilizing CD-Meth. The synthesized material showed promising selectivity and faster settling of hematite particles, surpassing conventional starch flocculants in all aspects.
The present work is focused on the development of a novel flocculant for selective flocculation of iron ore using functionalized beta-cyclodextrin (beta CD). beta CD has been modified by esterification reaction with methacrylic anhydride (MAh) to form beta CD methacrylate (CD-Meth). After that, a three-dimensional polymeric network structure has been prepared by free radical polymerization of CD-Meth with copolymeric chain of poly (acrylamide-co-acrylic acid) through grafting. The synthesized material has been characterized in detail. It has been found that the developed material has promising selectivity toward the hematite particles and also demonstrates faster settling of hematite particles. The developed material is found to be superior in all aspects than that of conventional selective flocculant used for iron ore beneficiation (i.e., starch).

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