Journal
ORGANOMETALLICS
Volume 40, Issue 6, Pages 627-634Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.1c00009
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Funding
- IISER Tirupati
- SERB of India [CRG/2018/002480/OC]
- SwarnaJayanti Fellowship grants [DST/SJF/CSA-04/2019-2020, SERB/F/5892/2020-2021]
- SERB [EMR/2016/006106]
- UGC
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The general and efficient C(alpha)-alkylation of oxindoles with unactivated secondary alcohols as alkylating agents catalyzed by a newly developed NNN-Mn(II) complex demonstrates the importance of the NH moiety in the complex and M-L cooperation during the catalytic transformation.
A general and efficient C(alpha)-alkylation of oxindoles with unactivated secondary alcohols as alkylating agents catalyzed by a newly developed NNN-Mn(II) complex is reported. Mechanistic studies illustrate that the importance of the NH moiety in the complex and M-L cooperation play very important roles during the catalytic transformation.
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