Journal
ORGANIC LETTERS
Volume 23, Issue 4, Pages 1349-1354Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c00011
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Funding
- JSPS KAKENHI [JP 19K15586, JP 17H06092]
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In this study, a series of axially chiral bibenzo[b]carbazole derivatives were successfully synthesized with circularly polarized luminescence (CPL) characteristics. These compounds exhibited CPL properties with large dissymmetry factors up to 2.81 x 10(-2) in the solid state, suggesting the formation of well-ordered aggregates.
Pure organic materials with the circularly polarized luminescence (CPL) property have attracted significant research interest over the past few decades. In this study, a series of axially chiral bibenzo[b]carbazole derivatives were synthesized by adopting palladium- and iridium-catalyzed direct C-H functionalization reactions as the key steps. These compounds exhibited CPL characteristics with considerably large dissymmetry factors up to 2.81 x 10(-2) in the solid state, indicating the formation of well-ordered aggregates.
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