Journal
ORGANIC LETTERS
Volume 23, Issue 6, Pages 2094-2098Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c00251
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Funding
- European Research Council (Horizon 2020) [VINCAT CoG 682002]
- Austrian Science Fund [P32607, J 4202N28]
- Boehringer Ingelheim
- University of Vienna
- Austrian Science Fund (FWF) [P32607] Funding Source: Austrian Science Fund (FWF)
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A formal enone alpha-arylation reaction is achieved through metal-free transformation mediated by I(III), involving the skeletal reorganization of silyl enol ethers. The reaction conditions are mild, leading to good yields and high stereoselectivity for beta-substituted enones.
A formal enone alpha-arylation is described. This metal-free transformation relies on the I(III)-mediated skeletal reorganization of silyl enol ethers and features mild conditions, good yields, and high stereoselectivities for beta-substituted enones.
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