Journal
MOLECULES
Volume 26, Issue 4, Pages -Publisher
MDPI
DOI: 10.3390/molecules26040790
Keywords
double-decker cerium complex; octacationic complex; redox switching
Funding
- JSPS KAKENHI [19H00902, 19H02787]
- JST PRESTO [JK114b]
- Grants-in-Aid for Scientific Research [19H00902, 19H02787] Funding Source: KAKEN
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A novel double-decker porphyrin complex with reversible redox behavior was prepared and shown to exhibit redox switching between oxidized and reduced states in organic solvents.
A novel double-decker porphyrin complex, bis{meso-tetrakis(4-N-alkylpyridiniumyl)porphyrinato}cerium, was prepared. Electrochemical measurements revealed that this complex exhibited reversible redox waves corresponding to a 1e(-) redox reaction of the cerium center. Treating the complex alternately with an oxidant and a reductant resulted in the reversible redox switching between the oxidized and reduced states in an organic solvent.
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