Theoretical Estimate of the Glass Transition Line of Yukawa One-Component Plasmas

The mode coupling theory of supercooled liquids is combined with advanced closures to the integral equation theory of liquids in order to estimate the glass transition line of Yukawa one-component plasmas from the unscreened Coulomb limit up to the strong screening regime. The present predictions constitute a major improvement over the current literature predictions. The calculations confirm the validity of an existing analytical parameterization of the glass transition line. It is verified that the glass transition line is an approximate isomorphic curve and the value of the corresponding reduced excess entropy is estimated. Capitalizing on the isomorphic nature of the glass transition line, two structural vitrification indicators are identified that allow a rough estimate of the glass transition point only through simple curve metrics of the static properties of supercooled liquids. The vitrification indicators are demonstrated to be quasi-universal by an investigation of hard sphere and inverse power law supercooled liquids. The straightforward extension of the present results to bi-Yukawa systems is also discussed.

Automated summary

The study combines mode coupling theory of supercooled liquids with the integral equation theory of liquids to estimate the glass transition line of Yukawa plasmas, from unscreened Coulomb limit to strong screening regime. The predictions improve upon current literature and confirm the validity of an existing analytical parameterization. It identifies structural vitrification indicators and demonstrates their quasi-universal nature through investigation of different types of supercooled liquids.