4.6 Review

Organic Semiconductor Micro/Nanocrystals for Laser Applications

Journal

MOLECULES
Volume 26, Issue 4, Pages -

Publisher

MDPI
DOI: 10.3390/molecules26040958

Keywords

organic molecules; single crystals; molecular packing; lasers; optical resonators

Funding

  1. Agencia Estatal de Investigacion (AEI, Spain) [PID2019-105479RB-I00]
  2. Severo Ochoa Programme for Centres of Excellence in RD (MINECO) [SEV-2016-0686]
  3. Spanish Ministry of Science, Innovation and Universities [RTI2018-097508B-I00]
  4. Regional Government of Madrid [NMAT2D S2018/NMT4511]

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Organic semiconductor micro/nanocrystals (OSMCs) have gained significant attention for their advantages such as lack of grain boundaries, minimal defects, molecular diversity, low cost, flexibility, and solution processability, making them strong contenders for the next generation of electronic and optoelectronic devices. Research in this area has focused on molecular packing, methods for controlling crystallization, and applications in organic solid-state lasers, with particular emphasis on OSMC lasers that self-assemble into geometrically defined optical resonators for tuning light emission properties through resonator design. The review also highlights the latest developments and novel strategies for tuning light emission and improving light extraction efficiency.
Organic semiconductor micro/nanocrystals (OSMCs) have attracted great attention due to their numerous advantages such us free grain boundaries, minimal defects and traps, molecular diversity, low cost, flexibility and solution processability. Due to all these characteristics, they are strong candidates for the next generation of electronic and optoelectronic devices. In this review, we present a comprehensive overview of these OSMCs, discussing molecular packing, the methods to control crystallization and their applications to the area of organic solid-state lasers. Special emphasis is given to OSMC lasers which self-assemble into geometrically defined optical resonators owing to their attractive prospects for tuning/control of light emission properties through geometrical resonator design. The most recent developments together with novel strategies for light emission tuning and effective light extraction are presented.

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