Dehydration behavior of a natural hydrated Ca-chabazite studied by in-situ high-temperature single-crystal X-ray diffraction

Dehydration behavior of a natural hydrated Ca-chabazite with composition (Ca(1.57)Na(0.4)9)(Al3.39Si8.55)O-24.12.47H(2)O has been studied by the structure analyses based on the in-situ high-temperature single-crystal Xray diffraction data at 100, 200 and 250 degrees C. Among the five water sites (OW1-OW5) and four exchangeablecation sites (Ca1-Ca4) found previously in the room-temperature (RT) structure, the present structure ana lyses revealed the presence of OW1, OW4, Ca3 sites at 100 degrees C and of OW3, Ca3, Ca4 sites at 200 and 250 degrees C. The presence of the new extraframework sites was also revealed: OW2' site at 100 degrees C and Ca5 site at 200 and 250 degrees C. From the temperature dependence of the occupation for these extraframework sites, the dehydration and cation migration processes are summarized and rationalized as follows. With heating up to 100 degrees C, OW3 water molecules, having no bonds to exchangeable cations, are completely desorbed. Simultaneously, Ca1 and Ca2 cations lose the large amounts of water molecules as ligands (OW1 and OW5 for Ca1, OW4 for Ca2); this brings about the simultaneous migration of both cations to adjacent Ca3 site, surrounded by more ligands. With further heating up to 250 degrees C, OW2' water molecules, having no bonds to exchangeable cations, are completely desorbed. Simultaneously, most of the Ca3 cations migrate to adjacent Ca4 and Ca5 sites by losing the large amounts of water molecules as ligands (OW1, OW4). A part of the water molecules desorbed in the temperature range of 100-250 degrees C migrate to OW3 site to be bonded to the remaining Ca3 cations. The peculiar temperature dependence of Si/Al O1, O2 and O3 bond lengths in the framework structure can be explained in terms of their bond-valence variations due to such dehydration and cation migration processes. On the other hand, the variation of Si/Al-O4 bond length is dominated by thermal expansion effect rather than the bond valence effect.

Automated summary

The dehydration behavior of a natural hydrated Ca-chabazite has been studied by in-situ high-temperature single-crystal X-ray diffraction data at different temperatures. The temperature-dependent migration of water molecules and cations in the structure, as well as the discovery of new extraframework sites, have been summarized and rationalized. The peculiar temperature dependence of Si/Al-O bond lengths in the framework structure was explained by the bond-valence variations due to dehydration and cation migration processes.