Enhanced activity of Ru-Ir nanoparticles over SiC for hydrogenation of levulinic acid at room-temperature

The hydrogenation of levulinic acid (LA) to gamma-valemlactone (GVL) under mild condition is a promising but challenging process. Herein, SiC supported Ru-Ir bimetallic catalyst exhibit enhanced catalytic activity for aqueous hydrogenation of LA into GVL under mild conditions. Comparing with monometallic Ir-3/SiC and Ru-3/SiC, the conversion of LA over bimetallic Ru-0.5-Ir-2.5/SiC catalyst increase from 51.2 % and 45.9% to 100% at 25 degrees C and 0.2 MPa of H-2 pressure. The enhanced catalytic activity of Ru-0.5-Ir-2.5/SiC catalyst originates from the electronic synergistic effect among Ru, Ir and SiC. Due to the electron transfer, electron-richened Ir nanoparticles show stronger ability for H-2 dissociation, and the SiC surface produces more active sites to accommodate hydrogen species that spill over from Ir and Ru. The adsorption and hydrogenation of LA molecules occur on the surface of SiC.

Automated summary

SiC supported Ru-Ir bimetallic catalyst shows enhanced catalytic activity for hydrogenation of levulinic acid into gamma-valemlactone under mild conditions. The enhanced activity is attributed to the electronic synergistic effect among Ru, Ir, and SiC.The adsorption and hydrogenation of levulinic acid molecules occur on the surface of SiC.