4.6 Article

Nd3+ doped BaAl2O4 for enhanced photocatalytic degradation of methylene blue

Journal

MATERIALS LETTERS
Volume 292, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.matlet.2021.129664

Keywords

Photocatalytic dye degradation; Barium aluminate; Neodymium; Methylene blue

Funding

  1. CONACYT [590749]

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The photocatalytic performance of neodymium doped barium aluminates in degrading methylene blue dye under solar radiation was studied, with superior degradation achieved with only 0.1 mol% Nd3+ doping. The photocatalyst with light Nd3+ doping showed a degradation rate three times faster than the undoped photocatalyst, indicating a nonlinear dependence of photoluminescence and photocatalytic activity on Nd3+ concentration.
Neodymium doped barium aluminates of hexagonal phase were prepared by combustion synthesis. The photocatalysts were characterized by X-ray diffraction, UV-Vis spectroscopy and photoluminescence spectroscopy. The photocatalytic performance of BaAl2O4:Nd3+ was evaluated through their role in the degradation of 15 ppm of methylene blue (MB) dye under solar radiation. Superior photocatalytic degradation of MB was achieved with only a 0.1 mol% Nd3+ doping percentage. The lightly Nd3+ doped photocatalyst rendered a degradation percentage rate that was three times faster than that of the undoped photocatalyst. The results suggest a nonlinear dependence of photoluminescence and photocatalytic activity on Nd3+ concentration. (C) 2021 Elsevier B.V. All rights reserved.

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