Journal
LETTERS IN ORGANIC CHEMISTRY
Volume 19, Issue 5, Pages 347-352Publisher
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/1570178618666210218212300
Keywords
Formamidine; DMF-DMA; Al-MCM-41; mesoporous materials; heterogeneous catalysis; formamidine derivatives
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Funding
- Directorate General for Scientific Research and Technological Development (DGRSDT)
- University of Tlemcen
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Formamidine derivatives were synthesized efficiently in this study using a cheap, stable, and non-toxic catalyst, Al-MCM-41, resulting in improved yields and solvent-free conditions.
Formamidine derivatives have been synthesized in excellent yields at room temperature from primary amine and N,N-dimethylformamide dimethylacetal (DMF-DMA) in the presence of a catalytic amount of Al-MCM-41 synthesized from natural bentonite as silica and aluminum source. The advantages of this method are the use of a cheap, stable, non-toxic, and readily available catalyst, easy work-up, improved yields, and solvent-free conditions.
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