Journal
JOURNAL OF POWER SOURCES
Volume 488, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2021.229456
Keywords
S-Polypyrrole composite; Ternary salt electrolyte; Li/li symmetric cell; Li-S batteries; Post mortem analysis
Funding
- Department of Science and Technology (DST), Govt. of India [IFA18-MS 153]
- SERB [SERB/NPDF/2017/000862/CS]
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The study demonstrates the synthesis of polypyrrole coated sulfur nanoparticles for high performance Li-S batteries, which effectively reduces capacity fading; The engineered structure can minimize rapid capacity decay and improve accessibility of sulfur to ions and electrons; The use of a specific electrolyte for Li anode protection results in the formation of a stable SEI layer, leading to increased discharge capacity and cycle life of the battery.
Lithium-sulfur batteries have been strongly advocated as prominent candidate for the next-generation energy storage device. The shuttling of lithium polysulfide (LiPS) during cycling is inherent problem in these batteries which results in huge capacity fading and impede their practical applications. A simple but effective method is adopted to synthesize polypyrrole coated sulfur nanoparticle which retard the LiPS dissolution in electrolyte. The polypyrrole coated continuous conducting network cathode with nano size (similar to 70 nm) sulfur particle and a stable solid electrolyte interface (SEI) layer protected anode for high performance Li-S battery is demonstrated in this study. Such engineered structure can minimize the fast capacity fading considerably and nano size sulfur makes themselves more accessible to ions and electrons. Strategically, for Li anode protection, LiPS based ternary salt electrolyte (Li2S6, LiNO3 and LiTFSI) is used which form a stable SEI-layer on Li anode during initial cycles. The composite cathode exhibit an initial discharge capacity of 1085 mAh g(-1) at 0.2 Ag-1 current density with a low capacity decay of 0.31% per cycles and cycled up to 165 cycles. The post-mortem analysis validates efficient trapping of LiPS in the cathode side and formation of a stable protective SEI layer on Li anode.
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