Ligand-Induced Motion and Self-Assembly Pathways between Nanocubes

Nanoparticle motion and self-assembly have been regarded as a promising pathway for forming ordered nanostructures. However, the detailed dynamics processes induced by ligand involvement remained poorly understood. Here, we used in situ liquid-cell electron microscopy technology to image the formation of face-to-face Pt cube ordered structures: pairs, linear chains, and squares. The van der Waals interaction between the two neighboring cubes was quantified in real time. Interestingly, the two different formation processes of the square phase were achieved via a rotational and translational method. It is found that the space between two neighboring cubes was the same as the ex-TEM results. The density functional theory calculation demonstrated that it was attributed to the DMF ligand interactions of the cubes that promoted their face-to-face attachment.

Automated summary

This study used in situ liquid-cell electron microscopy technology to observe the formation of face-to-face Pt cube ordered structures and found two different formation processes for the square phase. The results highlight the important role of ligand interactions in nanoparticle self-assembly.