Journal
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 12, Issue 8, Pages 2052-2056Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.0c03829
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Funding
- National Science Foundation [CHE-1953045]
- Chemical Sciences, Geosciences, and Bio-Sciences Division, Office of Basic Energy Sciences, Office of Science, US Department of Energy [DE-SC-0020168]
- DOE grant
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The singlet fission process in pentacene dimers mediated by a conical intersection can be controlled by coupling the molecule to a confined optical cavity photon mode, leading to significant suppression of singlet fission.
We demonstrate how the singlet fission process in pentacene dimers mediated by a conical intersection is controlled by coupling the molecule to a confined optical cavity photon mode. By following the polariton quantum dynamics of a conical intersection coupled to a cavity mode taking into account vibrational relaxation and cavity loss, we find that the singlet fission can be significantly suppressed because the polaritonic conical intersection is pushed away from the initial Franck-Condon excitation region.
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