Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 933, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2020.121653
Keywords
[Cp*Ru(eta(1)-ArCN)(3)]PF6 complexes; [Cp*Ru(eta(6)-arene)]PF6 complexes; X-ray structures; Interconversion; Catalysts for trans hydroboration
Categories
Funding
- Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan
Ask authors/readers for more resources
The synthesis and X-ray structures of three new [Cp*Ru(η1)-ArCN)(3)]PF6 (Ar = aryl) complexes are reported, which are thermally converted to [Cp*Ru(η6)-ArCN)]PF6 (Ar = aryl) sandwich complexes and subsequently recovered by UV light irradiation. Additionally, trans-selective hydroboration of internal alkynes using the synthesized complexes is disclosed.
The synthesis and X-ray structures of three new [Cp*Ru(eta(1)-ArCN)(3)]PF6 (Ar = aryl) complexes are reported. These complexes are thermally converted to [Cp*Ru(eta(6)-ArCN)]PF6 (Ar = aryl) sandwich complexes and subsequently recovered by UV light irradiation. The structures of the sandwich complexes are likewise determined. Trans-selective hydroboration of internal alkynes using the synthesized complexes is disclosed. (C) 2020 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
