Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 86, Issue 5, Pages 3989-3998Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c02837
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Funding
- National Natural Science Foundation of China [21002076]
- Scientific Research Foundation for the Returned Overseas Chinese Scholars
- Graduate Innovative Fund of Wuhan Institute of Technology [CX2019165]
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A new reaction was developed for the transition metal-free oxidative cross-coupling of activated olefins with N-alkyl amides, resulting in the formation of N-allylic amides in moderate to good yields. This reaction protocol was found to be applicable to various types of activated olefins.
The K2S2O8-mediated transition metal-free oxidative cross-coupling reaction of activated olefins with N-alkyl amides was developed, and the reaction gave N-allylic amides in moderate to good yield. This reaction protocol was suitable for different kinds of activated olefins.
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