XPS analysis of bridging and non-bridging oxygen in Yb3+-Er3+-Tm3+-doped zinc-tellurite glasses

Influence of Er3+, Yb3+ and Tm3+ on the network structure of zinc-tellurite glasses is investigated by refraction index and high-resolution X-ray photoelectron spectroscopy (XPS) in order to clarify the role of rare-earth ions in the formation of non-bridging and bridging oxygens (NBO and BO, respectively). The NBO atoms were responsible for high polarizability, as confirmed from the correlations between the local structure and polarizability, where have been tentatively established high linear fit r(2) =0.96 and 0.98 when the excitation wavelengths are 532 and 632.8 nm, respectively. The structural origin of the NBO atoms into the zinc-tellurites glasses is discussed by analysis of the component number from the deconvolution in the XPS spectra. In this analysis, Te 3d peaks shift by about 0.23 eV towards higher binding energy from TZ1 to TZ4, and spin-orbit splitting between Te 3d(5/2) and Te 3d(3/2) to all glasses remain unchanged, Delta E approximate to 10.4 eV. While Zn 2p peaks shift by about 1.08, eV towards higher binding energy, and spin-orbit splitting between Zn 2p(3/2) and Zn 2p(1/2) increase of 23.08 eV (TZ1 to TZ3) to 24.09 eV (TZ4) whit the increase REI. The O 1s spectra suggest that the increase of REI concentration produces additional environments for REI with bonds through lone-pair electrons, favoring the formation of NBOs. It was observed that the increasing the concentrations of REI has a high linear dependence with increased of NBO atoms in the glass network, r(2) =0.87.

Automated summary

The influence of Er3+, Yb3+, and Tm3+ on the network structure of zinc-tellurite glasses was investigated through refractive index and high-resolution X-ray photoelectron spectroscopy (XPS). The rare-earth ions were found to play a crucial role in the formation of non-bridging oxygen (NBO) atoms. XPS analysis showed that an increase in rare-earth ion concentration led to the promotion of NBO formation in the glass network.