Journal
ENERGY CONVERSION AND MANAGEMENT
Volume 119, Issue -, Pages 453-462Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.enconman.2016.04.071
Keywords
Sodium silicate; Rice husk; Heterogeneous catalyst; Transesterification; Biodiesel
Categories
Funding
- Thailand Graduate Institute of Science and Technology [TGIST 01-55-011]
- National Science and Technology Development Agency (NSTDA) - Thailand
- Suranaree University of Technology - Thailand
- Thailand Research Fund - Thailand [IUG5180010]
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In the present work, rice husk-derived sodium silicate was prepared and employed as a solid catalyst for simple conversion of oils to biodiesel via the transesterification reaction. The catalyst was characterized by TG-DTA, XRD, XRF, FT-IR, SEM, BET and Hammett indicator method. Under the optimal reaction conditions of catalyst loading amount of 2.5 wt.%, methanol/oil molar ratio of 12:1, the prepared catalysts gave 97% FAME yield in 30 min at 65 degrees C, and 94% FAME yield in 150 min at room temperature. The transesterification was proved to be pseudo-first order reaction with the activation energy (Ea) and the frequency factor (A) of 48.30 kJ/mol and 2.775 x 10(6) min(-1) respectively. Purification with a cation exchange resin efficiently removed all soluble ions providing high-quality biodiesel product that meets all the ASTM and EN standard specifications. Rice husk-derived sodium silicate showed high potential to be used as a low-cost, easy to prepare and high performance solid catalyst for biodiesel synthesis. (C) 2016 Elsevier Ltd. All rights reserved.
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