Journal
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 886, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2021.115119
Keywords
Graphene oxide; Starch; Carbon nanosheets; Electrostatic self-assembly; Supercapacitor
Categories
Funding
- Funds for the Central Universities [2572019BC13]
- National Undergraduate Innovative and Entrepreneurial Training Program [202010225116]
Ask authors/readers for more resources
A convenient method for synthesizing 2D porous carbon nanosheets from cationic starch using electrostatic self-assembly with KOH activation is reported. The resulting PCNs-1 exhibit high specific capacitance and remarkable electrochemical stabilization, showing potential in aqueous electrolytes.
Two-dimensional (2D) porous carbon nanosheets (PCNs) have drawn tremendous concern due to they possess large specific surface area, reduced ion transportation resistance and shorten ion diffusion distance. However, the traditional template method is complex and time-consuming. Here, we reported a convenient strategy to synthesize 2D PCNs derived from cationic starch using graphene oxide (GO) as template through an electrostatic self-assembly strategy with KOH activation. Due to the unique 2D highly interconnected nanosheet-like porous framework with suitable specific surface area, the as-prepared PCNs-1 electrode delivers high specific capacitance (232.1 F g?1 at 2 mV s?1) and impressive electrochemical stabilization (100.3% retention after 10,000 cycles) in 6 M KOH aqueous electrolyte. Meanwhile, the constructed PCNs-1//PCNs-1 symmetrical supercapacitor shows an energy density of 19.2 Wh kg?1 and remarkable electrochemical stabilization (93.7% retention after 10,000 cycles) in 1 M Na2SO4 aqueous electrolyte. The strategy provides a novel and convenient approach to construct porous carbon nanosheets for supercapacitors.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available