Photoswitchable surface wettability of ultrahydrophobic nanofibrous coatings composed of spiropyran-acrylic copolymers

polymeric coatings displayed water droplet contact angles in the range of 60-93?, which could reversibly be switched to 55-86? upon UV light (365 nm) illumination as a result of isomerization of the hydrophobic spiro form to the zwitterionic merocyanine form. The nanofibrous coatings prepared by electrospinning method displayed higher contact angles in the range of 120-136?, which was switched to 78-105? upon UV light irradiation. The developed photo-responsive coatings displayed highly-efficient photoswitching between the two hydrophobic and hydrophilic states as a response to UV and visible light irradiation. The photoswitchable nanofibrous coatings displayed ultrahydrophobic characteristics, where the colored water droplets were stable on their surface and could easily be adsorbed by a cellulosic tissue. In summary, the photoswitchable nanofibrous coatings could be applied for design and development of ultrahydrophobic materials with the ability of photo-controlling of surface wettability by light irradiation Hypothesis: Light-controlling of surface characteristics in polymeric coatings has been a significant research area because of its potential application in development of smart surfaces. Wettability of light-responsive polymeric coatings based on spiropyran photochromic compound could be tuned by light irradiation. This is mainly because of spiropyran isomerization between the hydrophobic and hydrophilic states. Experiments: Light-responsive latex nanoparticles containing spiropyran moieties were synthesized by semi-continuous emulsion copolymerization of acrylate monomers, which have different chain flexibility depending on the copolymer composition. Photochromic properties of spiropyran in stimuli-responsive latex nanoparticles displayed dependence of photochromism intensity and its kinetics to flexibility of the polymer chains in addition to the polarity of media. Photoswitchable surface wettability of the spiropyran-containing acrylic copolymer coatings was investigated, where the photo-responsive coatings were prepared by solution casting and electrospinning methods. Findings: The photoswitchable coatings prepared by solution casting and electrospinning methods showed significant differences in their physical characteristics and especially surface wettability. The

Automated summary

Polymeric coatings with photo-responsive properties can switch between hydrophobic and hydrophilic states through light irradiation, displaying ultrahydrophobic characteristics. This technology has great potential in the development of smart surfaces.