4.7 Article

Design and synthesis of NiCo/Co4S3@C hybrid material with tunable and efficient electromagnetic absorption

Journal

JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 583, Issue -, Pages 321-330

Publisher

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2020.09.054

Keywords

NiCo/Co4S3@C; Electromagnetic absorption properties; Interfacial polarization; Effective absorption bandwidth

Funding

  1. Qingchuang Talents Induction Program of Shandong Higher Education Institution (Research and Innovation Team of Structural-Functional Polymer Composites)
  2. Natural Science Foundation of Shandong Province [ZR2019YQ24]
  3. National Natural Science Foundation of China [51407134, 51801001]
  4. China Postdoctoral Science Foundation [2016 M590619, 2016 M601878]
  5. Provincial Key Research and Development Program of Shaanxi [2019GY197]
  6. Thousand Talents Plan
  7. World-Class University and Discipline
  8. Taishan Scholar0s Advantageous and Distinctive Discipline Program of Shandong Province
  9. World-Class Discipline Program of Shandong Province

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A novel carbon-coated NiCo alloy/Co4S3 hybrid material was fabricated in this study, with improved electromagnetic wave absorption properties achieved by adjusting the annealing temperature. The results suggest that the hybrid material has potential applications as an electromagnetic wave absorber.
Producing electromagnetic wave absorbers with high absorption capacity and wide absorption bandwidth is still a challenge task, which limits its application in human life. In this study, a novel carboncoated NiCo alloy/Co4S3 hybrid material was fabricated by a simple strategy. By adjusting the annealing temperature, the electromagnetic wave absorption property of NiCo/Co4S3@C hybrid material can be further improved. Herein, the NiCo/Co4S3@C hybrid material obtained at 750 degrees C exhibits satisfactory electromagnetic wave absorption performance. The minimum reflection loss value of -56.96 dB is obtained at 10.32 GHz, and the matching thickness is only 2.71 mm. When the thickness of the absorber is in the range of 1.8-5.0 mm, the effective absorption bandwidth is controlled between 4.64 and 18 GHz. The satisfactory properties of the hybrid materials are attributed to the space charge polarization caused by heterogeneous NiCo alloys, interfacial polarization between components and good impedance matching characteristics. The results show that NiCo/Co4S3@C hybrid material is a potential electromagnetic wave absorber. (C) 2020 Elsevier Inc. All rights reserved.

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