Journal
JOURNAL OF CLEANER PRODUCTION
Volume 288, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2020.125643
Keywords
Air activation; Phyllanthus emblica fruit Stone; Hydrothermal treatment; Activated carbon
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An eco-friendly and innovative approach was used to develop activated carbon from hydrothermally treated material from Phyllanthus emblica fruit stone. Comparisons were made between activated carbons developed from hydrothermally treated and untreated Phyllanthus emblica fruit stone, showing that hydrothermal treatment resulted in activated carbon with higher surface area and pore volume. This study introduces a new prospect for the development of better porous material through economical hydrothermal treatment.
An eco-friendly, advent, and innovative approach has been applied for the sustainable development of hydrothermally treated material from Phyllanthus emblica fruit stone (PEFS) to develop activated carbon. PEFS which is economical and has no significant value was typically used as a precursor for hydrothermal treatment at a low pressure utilizing an ordinary cost-effective hydrothermal autoclave. The hydrothermally treated Phyllanthus emblica fruit stone (HTPEFS) so developed was used for the production of activated carbon in an oxidising atmosphere (air). The morphological structure, textural properties and functional groups of the raw PEFS, HTPEFS and activated carbon prepared from HTPEFS were characterised by ICP, FT-IR, TGA, XRD, FE-SEM and BET analysis. To demonstrate the significance of the hydrothermal treatment, in this study a comparison has been made for activated carbons developed from hydrothermally treated Phyllanthus emblica fruit stone, and without hydrothermally treated Phyllanthus emblica fruit stone under similar experimental condition (400 degrees C, 90 min). The BET surface area and the total pore volume of activated carbon developed from hydrothermally treated Phyllanthus emblica fruit stone (569 m(2)g(-1), 0.342 cm(3)g(-1)) was comparatively higher than without hydrothermally treated Phyllanthus emblica fruit stone (486 m(2)g(-1), 0.289 cm(3)g(-1)). Hydrothermal treatment removes inorganic constituents from the biomass and consequently decreases reactivity resulting in the development of activated carbon having a well-developed surface area and pore volume. This study introduced a new prospect for the development of better porous material after hydrothermal treatment at a low pressure by exploiting economical autoclave. (C) 2020 Elsevier Ltd. All rights reserved.
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