4.7 Article

Control of slag formation in the electric furnace smelting of ferronickel for an energy-saving production

Journal

JOURNAL OF CLEANER PRODUCTION
Volume 287, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2020.125082

Keywords

Laterite; RKEF process; Ferronickel; Slag formation; Quaternary basicity; Energy-saving

Funding

  1. National Natural Science Foundation of China [51904341]
  2. National Key Research and Development Program of China [2017YFB0304301]
  3. China Postdoctoral Science Foundation [2020T130730]
  4. Hunan Provincial Natural Science Foundation of China [2019JJ50806]

Ask authors/readers for more resources

This study verified the feasibility of decreasing smelting temperature by controlling slag formation for energy-saving production, upgraded the slag regulation method, effectively reducing energy consumption and carbon dioxide emissions.
Two-thirds of the global nickel output can be attributed to the rotary kiln-electric furnace process. Due to the high contents of MgO and SiO2 in laterite, a high temperature (similar to 1600 degrees C) and corresponding energy (approximately 14 GJ/t-ferronickel) are required during the electric furnace smelting. This work verifies the feasibility of decreasing the smelting temperature by controlling the slag formation for an energy-saving production. The slag regulation method was upgraded through the coordination of the quaternary basicity [ = R-4 = m(CaO + MgO)/m(SiO2+Al2O3)] and FeO content. The melting temperature was decreased, and the melting rate of the feed was increased after slag control, owing to the generation of diopside and olivine eutectics instead of olivine and pyroxene. The viscosity of the slag was decreased, thus lowering the required smelting temperature. After regulating the quaternary basicity from 0.58 to 0.61 and the FeO content from 5.0 to 12.5 wt% in the final slag, the smelting temperature decreased by 86 degrees C. The energy consumption decreased from 13.75 to a minimum of 11.16 GJ/t-ferronickel. Furthermore, a long-term industrial practice (annual output: 0.24 million tons of ferronickel) demonstrated that the total energy consumption could be decreased by 0.16 million GJ a year, which is equivalent to reducing carbon dioxide emissions by 45 kilotons a year. (C) 2020 Elsevier Ltd. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available