Journal
JOURNAL OF APPLIED POLYMER SCIENCE
Volume 138, Issue 29, Pages -Publisher
WILEY
DOI: 10.1002/app.50694
Keywords
films; morphology; nanostructured polymers; nanotubes; graphene and fullerenes; theory and modeling
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Funding
- Projekt DEAL
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This study fabricated PMMA/GNPs conductive composite films with different morphologies using four fabrication techniques and systematically investigated the morphologies of dispersed GNPs and their electrical properties in both in-plane and perpendicular direction. The percolation thresholds and conductivities of the composites varied significantly with different fabrication techniques, and the differences were explained in terms of GNPs size, orientation, distribution, and dispersion state.
In this study, poly(methyl methacrylate) (PMMA)/graphene nanoplatelets (GNPs) conductive composite films with different morphologies were fabricated from the same constituent materials using four fabrication techniques, solution casting (SC), SC followed by hot pressing (SCP), melt mixing followed by SC (MSC), and melt mixing followed by hot pressing (MP). Morphologies of dispersed GNPs and electrical properties in both in-plane and perpendicular direction were investigated and compared systematically. The corresponding percolation thresholds (phi(c)) of the composites varied from 0.42 +/- 0.13 vol% to 3.26 +/- 0.48 vol%. The conductivities varied up to two orders of magnitude and decreased in the sequence of SC > MSC > SCP > MP. These variations were explained in terms of GNPs size, GNPs orientation, distribution and dispersion state of fillers. The contribution of the above factors in each procedure were discerned individually, the results were discussed and compared with other experimental studies and simulations as well.
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