4.6 Article

Piezoelectric properties of PVDF-conjugated polymer nanofibers

Journal

JOURNAL OF APPLIED POLYMER SCIENCE
Volume 138, Issue 28, Pages -

Publisher

WILEY
DOI: 10.1002/app.50665

Keywords

conducting polymers; electrochemistry; fibers; radical polymerization; sensors and actuators

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This study developed and characterized PVDF-conjugated polymer nanofiber-based systems, with PVDF/PPY nanofiber system exhibiting the highest piezoelectric performance. These systems show potential as an attractive source of energy for various devices.
This study presents the development and characterization of PVDF-conjugated polymer nanofiber-based systems. Five different conducting polymers (CPs) were synthesized successfully and used to create the nanofiber systems. The CPs used are polyaniline (PANI), polypyrrole (PPY), polyindole (PIN), polyanthranilic acid (PANA), and polycarbazole (PCZ). Nanofiber systems were produced utilizing the Forcespinning (R) technique. The nanofiber systems were developed by mechanical stretching. No electrical field or post-process poling was used in the nanofiber systems. The morphology, structure, electrochemical and piezoelectric performance was characterized. All of the nanofiber PVDF/CP systems displayed higher piezoelectric performance than the fine fiber PVDF systems. The PVDF/PPY nanofiber system displays the highest piezoelectric performance of 15.56 V. The piezoelectric performance of the PVDF/CP nanofiber systems favors potential for an attractive source of energy where highly flexible membranes could be used in power actuators, sensors and portable, and wireless devices to mention some.

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