4.7 Article

Silicate-assisted activation of biomass towards N-doped porous carbon sheets for supercapacitors

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 853, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2020.157091

Keywords

Carrots; Activation; Porous structure; N-doping; Supercapacitor

Funding

  1. National Natural Science Foundation of China [21676070]
  2. Hebei Province Introduction of Foreign Intelligence Projects
  3. Beijing National Laboratory for Molecular Sciences, Hebei Science and Technology Project [20544401D, 20314401D]
  4. Tianjin Science and Technology Project [19YFSLQY00070]
  5. CAS Key Laboratory of Carbon Materials [KLCMKFJJ2007]

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Research on nitrogen-enriched porous carbons synthesized from carrot biomass using a simple silica activation process shows promising characteristics for energy storage applications, with features like easy operation, low cost, and outstanding performance in supercapacitors.
Biomass-derived carbon has been the focus of research for a long time due to its wide range of sources, rich diversity and low cost. However, it also faces poor pore size distribution, low surface area and inert surface, which leads to its low performance, especially in supercapacitor. Herein, nitrogen enriched porous carbons (N-PC) were synthesized via a simple silica-activation process using carrots biomass as carbon precursor and Na2SiO3 as effective activation agent. Direct grinding for mixing of carrots and Na2SiO3 avoids the utilization of any solvents, leading to the characteristics of easy operation, simplicity and large-scale application. Carrots are rich in vitamins, which makes them serve as excellent carbon and nitrogen precursor. The low-cost Na2SiO3 plays an activating role to create porous structure, realizing the adjustment of mesopore size and increasing surface area for the N-PC. The prepared N-PC exhibits layered morphology, high surface area, rich porous structure, and nitrogen doping, which endow the N-PC with outstanding performance in the field of supercapacitor, indicating its promising for energy storage application. (c) 2020 Elsevier B.V. All rights reserved.

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