4.4 Article

Preparation and properties of a novel wood adhesive derived from antibiotic bacterial residues

Journal

JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY
Volume 35, Issue 22, Pages 2466-2482

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/01694243.2021.1890371

Keywords

Antibiotic bacterial residues; crosslinking; water resistance; epoxy resin; wood adhesive

Funding

  1. University-Industry Cooperation Research Project in Henan Province [182107000006]
  2. Key R & D and promotion projects in Henan Province [202102310601]

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The study explored the potential of using antibiotic bacterial residues (ABR) in the development of wood adhesives. A new wood adhesive based on ABR was prepared by modifying ABR with NaOH, polyacrylamide (PAM), and sodium dodecyl benzene sulfonate (SDBS), with epoxy resin (EP) used as a crosslinking agent. The experimental results showed that the optimal conditions for the adhesive included specific amounts of ABR, PAM, NaOH, SDBS, and EP, which directly impacted the water resistance, mechanical strength, and thermal stability of the adhesive. Application of the ABR adhesive in plywood production resulted in meeting the requirements for interior-use plywood wet shear strength.
Due to an increased understanding of the potential applications of antibiotic bacterial residues (ABR), these resources have been investigated for use in the development of ABR-based wood adhesives. In this study, ABR were modified using NaOH, polyacrylamide (PAM), and sodium dodecyl benzene sulfonate (SDBS) to prepare a novel wood adhesive with epoxy resin (EP) as crosslinking agent. Characteristics of the ABR-based wood adhesive were investigated based on its solid content, viscosity, insoluble matter, moisture absorption rate, and both dry and wet shear strength. Fourier transform infrared (FTIR), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and scanning electron microscopy (SEM) were used for characterization of the ABR-based wood adhesive. Experimental results show that the optimal condition was as follows: 50 g ABR, 0.75 g PAM (0.5%), 0.5 g NaOH, SDBS (5 g, 10% wt.), and 20% EP. The EP content was found to directly affect the water resistance, mechanical strength and thermal stability of the adhesive. Application of the ABR adhesive synthesized under these optimal conditions to form plywood, resulted in a wet shear strength of 1.38 MPa, meeting the requirements of interior-use plywood. Therefore, this study indicates that ABR resources have good prospects and possibilities for use in ABR-based wood adhesives, in applications, such as plywood production.

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