Al-substituted stable-layered P2-Na0.6Li0.15Al0.15Mn0.7O2 cathode for sodium ion batteries

P2-type Mn-based layered oxides have been considered as one of the most commercial potential cathodes for the sodium-ion batteries (SIBs) owing to the low cost, low toxicity, and abundant compositions. However, the P2-type cathode still possesses a lot of drawbacks, such as the unfavorable phase transition and poor-rate performance during the desosidation/sodiation process. Herein, we developed P2-Na0.6Li0.15Al0.15Mn0.7O2 as a promising sodium cathode with a stable performance. The batteries with this new cathode deliver 184.9 mAh/g initial reversible capacity at 0.2 C and exhibit preferable rate properties. By investigating multiple characterizations, the Al-substituted P2-Na0.6Li0.15Al0.15Mn0.7O2 is found to be absent of phase transition in the first cycle process from the ex-situ XRD characterization results. In addition, the surface charge transfer reactions have been also investigated. This work may shed substantial light on developing high-rate capability and stable Mn-based cathode materials for practical SIBs.

Automated summary

The study developed a stable P2-Na0.6Li0.15Al0.15Mn0.7O2 sodium cathode, which exhibited good rate performance and initial reversible capacity. Investigations into multiple characteristics revealed that this new cathode does not undergo phase transition during cycling processes.