4.7 Article

Hydrothermal synthesis of blue-green emitting carbon dots based on the liquid products of biodegradation of coal

Journal

INTERNATIONAL JOURNAL OF ENERGY RESEARCH
Volume 45, Issue 6, Pages 9396-9407

Publisher

WILEY
DOI: 10.1002/er.6468

Keywords

carbon dots; liquid products of coal biodegradation; pH-sensitive; temperature-sensitive

Funding

  1. National Natural Science Foundation of China [21103135, 21073139, 21301139, U1903133, 21373158]
  2. Natural Science Basic Research Plan in Shaanxi Province of China [2016JM2011, 2018JQ2061]
  3. Shaanxi innovative Talent Promotion Project [2017KJXX-55]

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A simple and low-cost method was described for preparing carbon dots (CDs) from the biodegradation liquid products of coal (LPBC) through hydrothermal treatment. The synthesized CDs exhibited strong fluorescence intensity, narrow size distribution, and stability, showing great promise in sensor applications. The fluorescence intensity of the CDs was sensitive to pH value and temperature, further enhancing their potential for sensing applications.
The liquid products of biodegradation of coal (LPBC) without further separation and purification are generally difficult to apply. In this study, a simple and low-cost method had been described for the preparation of carbon dots (CDs) by hydrothermal treatment of original LPBC. The as-synthesized CDs scence emission intensity when possessed narrowly distributed sizes and a mean diameter of 3.5 nm, and they showed significant excitation-dependent fluorescence emission. Meanwhile, the CDs exhibited good water solubility and photo-, metal ions-stability. Furthermore, the fluorescent emission intensity of CDs had been demonstrated sensitivity to pH value and temperature, showing great promise in sensor application.

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