Sodium Site Exchange and Migration in a Polar Stuffed-Cristobalite Framework Structure

The study of ionic dynamics in solids is essential to understanding and developing modern energy technologies. Here we study the ionic dynamics of orthorhombic Na2MgSiO4, an interesting case of a polar stuffed-cristobalite-type structure that contains two inequivalent Na sites within the channels of the magnesium silicate tetrahedral framework. Its preparation by a solid-state reaction method favors the presence of similar to 2% of Na vacancies, converting it into a pure Na ionic conductor with an optimized ionic conductivity of similar to 10(-5) S cm(-1) at 200 degrees C. The macroscopic migration has been characterized through impedance spectroscopy and molecular dynamics simulation, which proves the pure Na ionic character of the compound through hopping between Na1 and Na2 sites, forming three-dimensional migration zigzag-shaped paths. High-resolution solid-state Na-23 magic-angle-spinning (MAS) NMR spectroscopy is employed to characterize the local structure and microscopic dynamics of Na-ion transport in Na2MgSiO4. Remarkably, variable-temperature Na-23 MAS NMR and two-dimensional exchange spectroscopy evidence for the first time a Na site exchange phenomenon at room temperature, which further triggers Na ionic conduction at elevated temperatures.

Automated summary

The study focuses on the ionic dynamics of orthorhombic Na2MgSiO4, a compound that shows pure Na ionic conductivity and three-dimensional migration paths through a solid-state reaction method. Experimental methods including impedance spectroscopy, molecular dynamics simulation, and solid-state NMR spectroscopy are used to characterize the ionic behavior of Na ions within the compound.