A Photoluminescent Cd(II) Coordination Polymer with Potential Active Sites Exhibiting Multiresponsive Fluorescence Sensing for Trace Amounts of NACs and Fe3+ and Al3+ Ions

The elaborately designed p-electron-rich fluorescent ligand 1,4-bis(1-carboxy-methylene-4-imidazolyl)benzene (H2L), possessing bifunctional groups including the carboxylate groups (building units) and 4-imidazoyl groups (N-donor potential active sites) has been employed to construct fluorescent coordination polymers. A luminescent sensor, namely [Cd(L)(phen)(2)]center dot 5H(2)O (1), was obtained, which has a one-dimensional structure. The fluorescent material shows a blue emission maximum at 457 nm with a luminescence lifetime of 488 ns and a quantum yield (QY) of 4.56%. Significantly, 1 serves as a promising multiresponsive luminescent sensor to detect trace nitroaromatic compounds (NACs) with the limits of detection (LOD) of 7.21 x 10(-8), 1.85 x 10(-5), and 1.15 x 10(-5) mol/L for 2-nitrophenol (2-NP), 3-nitrophenol (3-NP), and 4-nitrophenol (4-NP), respectively. Furthermore, CP 1 exhibits fluorescent turn-off and turn-on sensing behavior for Fe3+ and Al3+ metal ions with trace amounts of 1.05 x 10(-7) and 1.13 x 10(-7) mol/L, respectively. Experimental methods and theoretical calculations were employed to elucidate the sensing mechanism in detail.

Automated summary

An elaborately designed fluorescent ligand was used to construct a one-dimensional luminescent sensor capable of detecting nitroaromatic compounds and metal ions with high sensitivity. Both experimental methods and theoretical calculations were employed to elucidate the sensing mechanism in detail.