4.7 Article

Effect of Sulfonamide and Carboxamide Ligands on the Structural Diversity of Bimetallic RhII-RhII Cores: Exploring the Catalytic Activity of These Newly Synthesized Rh2 Complexes

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Summary: Homoleptic dirhodium(II,II) paddlewheel complexes with the general formula Rh(2)A(4) have diverse applications in chemical research and industry, serving as catalysts, detectors, enzymatic inhibitors, or building blocks for molecular scaffolds. They are commonly used in organic synthesis to transfer electron-deficient species, activate unsaturated bonds, catalyze hydrogenation, and participate in oxidation/reduction processes. The complexes can be prepared from basic inorganic precursors or post-functionalization of paddlewheel structures, allowing modulation of electrochemical potential, geometry, and physical/chemical properties of the metal complex.

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