Journal
INDUSTRIAL CROPS AND PRODUCTS
Volume 160, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.indcrop.2020.113109
Keywords
Fractionation; UV-catalyzed hydrogen peroxide pretreatment; Sisal waste; Lignocellulosic fractions; Antioxidant activity
Categories
Funding
- National Natural Science Foundation of China [31371743]
- Science and Technology Planning Project of Guangdong Province, China [2016A050503017]
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An integrated fractionation process involving UV-catalyzed hydrogen peroxide pretreatment and extraction was developed to recover cellulose, hemicellulose, lignin, and liquid fractions from sisal waste. These fractions, with different characteristics, serve as a viable source of high-value industrial chemicals.
An integrated fractionation process, UV-catalyzed hydrogen peroxide pretreatment (UHP) with subsequent alkali and acidic ethanol extraction, was developed to consecutively recover cellulose, hemicellulose, lignin and pretreated liquid fractions from sisal waste. These fractions serve as a viable source of high-value industrial chemicals. Delignification rate reached approximately 80 % under the UHP pretreatment with 0.1 mL/g H2O2 for 6 h. The pretreated sisal waste was further fractionated into four parts, cellulose (35.5 g/100 g sisal waste), xylan-rich hemicellulose (12.5 g/100 g sisal waste), acid-insoluble lignin (5.7 g/100 g sisal waste) and the liquid fraction (21.0 g/100 g sisal waste). The cellulose fraction was in high purity with increased crystalline index of 51.4 %, and the hemicellulose fraction was rich in xylan. The lignin fraction had the GSH-type structure with some ferulic acid residues bound mainly via beta-O-4 linkages. The liquid fraction had a high content of phenolic compounds (16.26 similar to 41.88 mg GAE/L) with strong antioxidant activities, 11.16 similar to 18.48 mu mol TE/L reducing power, 66.78 similar to 82.84 mu mol TE/L hydroxyl radical scavenging and 14.83 similar to 46.67 mu mol TE/L ABTS radical scavenging.
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