4.6 Article

Photothermally Caused Propylene Glycol-Water Binary Droplet Evaporation on a Hydrophobic Surface

Journal

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 60, Issue 10, Pages 4153-4167

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.iecr.0c05873

Keywords

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Funding

  1. National Natural Science Foundation of China [51925601, 51620105011]
  2. Graduate Scientific Research and Innovation Foundation of Chongqing, China [CYB19060]
  3. Fundamental Research Funds for the Central Universities [2018CDXYDL0001]

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This study experimentally investigated the evaporation of a propylene glycol-water binary droplet induced by the photothermal effect of a focused infrared laser, revealing dynamic evaporation behaviors and discussing the effects of initial composition and input laser power. Results showed a two-stage evaporation process dominated by water and propylene glycol, providing insights into the potential applications of binary droplet evaporation.
Photothermal effect has shown great promise in manipulating the droplet evaporation. In this work, the evaporation of a propylene glycol-water binary droplet on the hydrophobic surface induced by the photothermal effect of a focused infrared laser with a wavelength of 1550 nm was experimentally investigated. Dynamic evaporation behaviors were discussed through the visualization method and image processing technique. Experimental results showed that the photothermally induced evaporation of such a binary droplet could be divided into two stages: the first stage dominated by the evaporation of water with more volatility represented by rapid variations of the droplet volume and geometric parameters and the second stage dominated by the evaporation of propylene glycol with less volatility represented by a smaller slope. Correspondingly, the binary droplet evaporation first experienced the mixed mode greatly related to the more volatile component, and then the constant contact radius mode greatly related to the less volatile component. In addition, the effects of the initial composition and input laser power were also discussed. This work provides a deep understanding of the photothermal effect of a focused light-caused evaporation behaviors of the propylene glycol-water binary droplets and a potential route to accommodate various applications using the evaporation of the binary droplet.

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