Journal
ENERGY
Volume 112, Issue -, Pages 294-306Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.energy.2016.06.088
Keywords
Butler-volmer equation; Lithium-ion batteries; Lithium titanate batteries; Electro chemical impedance spectroscopy; Hybrid pulse power characterization tests; Lithium
Categories
Funding
- European Commission [605485]
Ask authors/readers for more resources
This study shows results of extensive experimental measurements performed on high power lithium titanate based batteries. Characterization tests are performed over a wide temperature range (-20 degrees C - +40 degrees C) by employing electrochemical impedance spectroscopy and modified hybrid pulse power characterization tests. Furthermore, the behavior of battery impedance parameters over the battery lifetime with regard to temperature, State-of-Charge and their influence on available battery power in an example of electric vehicles is discussed. Based on extracted parameters, a reduced order equivalent circuit model considering the nonlinearity of the charge transfer resistance is parametrized. The obtained results indicate that ohmic resistance increases with decreasing State-of-Charge while the shape of the curve remains almost constant over the battery lifetime. The total impedance determined at 1 mHz shows almost no dependence on State-of-Charge and remains constant over the whole State-of-Charge range. The necessity of considering the impact of the current dependence of the direct current resistance at least at low temperatures (i.e., below 0 degrees C) is confirmed. Moreover, by investigating the Butler-Volmer equation the behavior of exchange current density and symmetry factor is analyzed for various temperatures and State-of-Charges over the battery lifetime. (C) 2016 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available