Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2021, Issue 14, Pages 2091-2098Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202100047
Keywords
Imidazolium; Ionic material; Liquid crystal; Luminescent; Naphtalene
Categories
Funding
- OUTSMART [A.N.R.-15-CE39-0004]
- Erasmus (Emma Scrafton Grant)
Ask authors/readers for more resources
This article describes an efficient synthetic pathway and the characterization of liquid crystal luminescent imidazolium salts based on a naphthalene unit. The study reveals the segregation between rigid ionic and flexible parts, leading to the emergence of mesomorphic properties. By varying the alkyl tail number, different architectures of self-organization in liquid crystal state can be induced.
In this article, we describe an efficient synthetic pathway and the characterization of liquid crystal luminescent imidazolium salts based on a naphthalene unit. The luminescent imidazolium-naphthalene rigid part is decorated with a benzyl group functionalized by two or three dodecyloxy chains. A crystalline structure shows unambiguously the segregation between the rigid ionic and flexible parts conducive to the emergence of mesomorphic properties. A complete thermotropic properties study of these salts has been carried out according to different anions. The alkyl tail number variation and therefore the amphipathic character (balance between hydrophilic/hydrophobic) makes it possible to induce liquid crystal state with different architectures of self-organization in layers (Smectic A) or columns (Columnar hexagonal). Finally, the photophysical properties were measured in solution and in the solid state at room temperature and showed photoluminescence quantum yields around 20 %.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available