4.5 Article

Phosphorescent Cyclometalated Platinum(II) Imidazolinylidene Complexes

Journal

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume 2021, Issue 9, Pages 804-813

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.202001077

Keywords

Imidazolinylidene ligands; Carbene ligands; Phosphorescence; Platinum; Structure elucidation

Funding

  1. Projekt DEAL

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A total of six novel platinum complexes were successfully synthesized from saturated N-heterocyclic carbene precursors, showing strong emissive properties in the sky-blue region of the visible spectrum with quantum yields up to 71% in a PMMA matrix. The structures were characterized by NMR experiments and solid-state analyses, confirming the cyclometalation and saturated backbone of the NHC motif. DFT calculations were used to examine the photophysical and electrochemical properties of the platinum complexes.
We present the synthesis and characterization of six novel bidentate C perpendicular to C* cyclometalated platinum(ii) complexes derived from saturated N-heterocyclic carbene precursors, namely 1-aryl-3-methyl-1H-4,5-dihydroimidazolium salts. The title compounds were then synthesized by a multi-step reaction, which includes an in situ generation of the silver carbene complex, followed by transmetalation to platinum and subsequent introduction of the beta-diketonate ligand. Structural characterization by NMR experiments and solid-state structures prove the cyclometalation and the saturated backbone of the NHC motif. Photophysical and electrochemical properties of the platinum(ii) complexes were examined and studied in detail by DFT calculations. The title compounds are strongly emissive at room temperature in the sky-blue region of the visible spectrum and show quantum yields of up to 71 % in a PMMA matrix.

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