Journal
ELECTROCHIMICA ACTA
Volume 370, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2021.137755
Keywords
Urea electro-oxidation; Nickel; nickel oxide; Graphene nanosheets; Annealing temperature
Categories
Funding
- National Natural Science Foundation of China [21972124, 21603041]
- Priority Academic Program Development of Jiangsu Higher Education Institution
- Top-notch Academic Programs Project of Jiangsu Higher Education Institutions
- Six Talent Peaks Project of Jiangsu Province [XCL-070-2018]
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This study successfully demonstrated phase structure tuning of graphene supported Ni-NiO nanoparticles system to enhance urea oxidation performance. By optimizing the annealing temperature, the sample obtained at 450 degrees Celsius exhibited the highest catalytic activity and stability.
The sluggish kinetics of urea electro-oxidation seriously limits its application in hydrogen production and wastewater treatment. Herein, we demonstrated an easy freeze-drying/annealing approach induced phase structure tuning of graphene supported Ni-NiO nanoparticles system for efficiently boosting urea oxidation performance. The annealing temperature was found significant to influence the Ni precursors decomposition, crystal structure formation and catalytic performance for urea oxidation. By increasing the temperature from 350 degrees C to 550 degrees C, more metallic Ni was formed in the Ni-NiO system, and because of the efficient Ni-NiO synergistic effect and conductivity improvement, the sample obtained at 450 degrees C exhibited the highest catalytic activity and stability for urea oxidation. Specifically, the current density at 0.5 V was 38.24 mA cm(-2), about 5.6 and 30 times of the control sample of graphene supported NiO and Ni respectively. Efficient kinetics and rapid charge transfer-ability were also found for urea oxidation by a series of electro-kinetics analysis. The current work showed an easy way for Ni-based catalyst structure tuning with enhanced kinetics for urea oxidation, which is helpful for the sustainable utilization of urea molecular in electrochemical energy. (C) 2021 Elsevier Ltd. All rights reserved.
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