Journal
DYES AND PIGMENTS
Volume 186, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2020.108996
Keywords
Spirooxazine; Colorimetric probe; Methylmercury; Mercuric ion; Mercury strip test
Funding
- Kasetsart University Research and Development Institute (KURDI)
- Center of Excellence for Innovation in Chemistry (PERCH-CIC), Ministry of Higher Education, Science, Research and Innovation
- Cluster and Program Management Office (CPMO, NSTDA-EGAT) [P1450309]
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6'-(indolin-1-yl)-1-(4-methoxybenzyl)-3,3-dimethylspiro[indoline-2,3'-naphtho[2,1-b][1,4]oxazine] (SPO) is a novel colorimetric probe with superior selectivity and sensitivity for CH3Hg+ detection in a 1,4-dioxane solution. Complexes of SPO with Hg2+ or CH3Hg+ were formed at a 1:1 mol ratio, with detection limits in the nM level in 1,4-dioxane. Test strips coated with SPO also showed highly sensitive detection of CH3Hg+ in mixed 1,4-dioxane:water solutions.
6'-(indolin-1-yl)-1-(4-methoxybenzyl)-3,3-dimethylspiro [indoline-2,3'-naphtho[2,1-b] [1,4]oxazine] (SPO), a novel colorimetric probe in a spirooxazine class, was successfully synthesized. Its molecular structure was confirmed by the single crystal and spectroscopic analyses. Upon UV activation, SPO in a 1,4-dioxane solution possessed superior selectivity and sensitivity for colorimetric detection of CH3Hg+ over other cations, including Hg2+. The results from the absorption study showed that the mixtures of SPO and Hg2+ or CH3Hg+ exhibited a new absorption band at 590 nm. This indicates the structural isomerization of SPO into an open-form merocyanine which acts as a ligand to form an SPO-Hg2+ or SPO-CH3Hg+ complex. The stoichiometric ratio of SPO to each mercuric cation in the complexes was determined using Job's method and the results suggested that the complexes were formed at a 1:1 mol ratio. The detection limit of Hg2+ and CH3Hg+ in 1,4-dioxane was investigated and the results showed the values at nM level (152 nM for Hg2+ and 150 nM for (CHHg+)-Hg-3). Moreover, the test strips coated with SPO were also demonstrated to provide a practically highly sensitive detection of CH3Hg+ in mixed 1,4-dioxane:water solutions.
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